Premier Foods, which bought Mr Kipling with its acquisition of RHM two years ago, is understood to have rejected the £250m approach.
The reported move comes as Premier - also owner of Hovis bread and Branston Pickle - comes under pressure over its heavy debt burdens, which stood at £1.8bn at the end of June. Premier has seen its shares tumble nearly 90 per cent in the past year. Mr Kipling has estimated sales of around £200m.
United could approach Premier's lenders or shareholders directly to convince the firm to do a deal, it is suggested.
Since 2006, United has been owned by private equity firms PAI and Blackstone.
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